Preconcentration Method on Modified Silica Fiber for Chromium Speciation
نویسندگان
چکیده
منابع مشابه
Preconcentration method on modified silica fiber for chromium speciation.
A new method involving pre-concentration on modified silica fiber is described for the speciation of chromium(III) [Cr(III)] and chromium(VI) [Cr(VI)] in aqueous media. This method is based on the different chelating behavior of Cr(III) and Cr(VI) with morpholine-4-carbodithioate (MDTC). Both complexes are extracted on silica fiber modified by sol-gel technology by using 3-aminopropyltriethoxys...
متن کاملOn-line micro column preconcentration system based on amino bimodal mesoporous silica nanoparticles as a novel adsorbent for removal and speciation of chromium (III, VI) in environmental samples
BACKGROUND Chromium (VI) has toxic and carcinogenic effects. So, determination and speciation of chromium in environmental samples is very important in view of health hazards. In this study, solid phase extraction (SPE) based on bulky amine-functionalized bimodal mesoporous silica nanoparticles (NH2-UVM-7) as a novel nanoadsorbent was applied for preconcentration and speciation of chromium (III...
متن کاملMetal Recovery and Preconcentration by Aminopolycarboxylic Acid modified Silica Surfaces
This study focuses on the adsorption and preconcentration of various metals by silica gel surfaces modified with aminopolycarboxylic acids namely ethylenediaminetetraacetic acid or diethylenetriamine-pentaacetic acid. The adsorption performance of the studied materials was determined in mixed metal solutions and the adsorption isotherm studies were conducted for cobalt, nickel, cadmium, and lea...
متن کاملPreconcentration and speciation of chromium in water samples by atomic absorption spectrometry after cloud-point extraction.
A rapid, sensitive and accurate atomic absorption method for Cr(III) and Cr(VI) ions was developed based on the cloud-point extraction (CPE) technique. Cr(III) reacts with a new Schiff's base ligand to form the hydrophobic complex, which is subsequently entrapped in the surfactant micelles. The Cr(VI) assay is based on its reduction to Cr(III) by the addition of concentrated H2SO4 and ethanol t...
متن کاملChromium(vi) Removal by Modified Pvp- Coated Silica Gel
This research involved the synthesizing of a reactive polymer, long alkyl quaternized poly(4-vinylpyridine) (PVP), and coating it on the surface of silica gel to produce a granular sorbent to remove Cr(VI) from water. Batch experiments were conducted to determine the kinetics, sorption isotherm, pH effects, and influence of other anions on the chromium adsorption onto the coated silica gel. The...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Chromatographic Science
سال: 2011
ISSN: 0021-9665,1945-239X
DOI: 10.1093/chromsci/bmr007